论文目录 | |
Acknowledgements | 第1-7页 |
Abstract | 第7-15页 |
摘要 | 第15-25页 |
Chapter 1. Literature review | 第25-59页 |
1.1 Introduction | 第25-28页 |
1.2 Burning rate | 第28-32页 |
1.2.1 Factors affecting burning rate of the propellant | 第28-31页 |
1.2.2 Modification of burning rate of the propellant | 第31-32页 |
1.2.3 Burning rate catalysts | 第32页 |
1.3 Synthesis of ferrocene-based burning rate catalysts | 第32-44页 |
1.3.1 Ferrocene-based polymers | 第32-41页 |
1.3.2 Ferrocene-based ionic compounds | 第41页 |
1.3.3 Ferrocene-based dendrimers | 第41-43页 |
1.3.4 Ferrocene derivatives | 第43-44页 |
1.4 Migration of ferrocene-based burning rate catalysts | 第44-46页 |
1.5 Catalytic mechanism of ferrocene-based burning rate catalysts | 第46-48页 |
1.6 Research objectiyes | 第48-50页 |
References | 第50-59页 |
Chapter 2. Synthesis,electrochemical and anti-migration properties of ferrocene-based polyethyleneimines and their application as burning rate catalysts | 第59-93页 |
2.1 Introduction | 第59-61页 |
2.2 Experimental | 第61-65页 |
2.2.1 Materials | 第61页 |
2.2.2 Schlenk line system | 第61-62页 |
2.2.3 Synthesis | 第62-63页 |
2.2.4 Characterization | 第63-65页 |
2.3 Results and discussion | 第65-87页 |
2.3.1 Synthesis and characterization of ferrocene-based polyethyleneimines | 第65-69页 |
2.3.2 Electrochemical properties of ferrocene-based polyethyleneimines | 第69-80页 |
2.3.3 Anti-migration studies of ferrocene-based polyethyleneimines | 第80-83页 |
2.3.4 Burning rate catalytic performance of ferrocene-based polyethyleneimes | 第83-85页 |
2.3.5 Possible catalytic mechanism of ferrocene-based burning rate catalysts on thermal decomposition of ammonium perchlorate | 第85-87页 |
2.4 Conclusion | 第87页 |
References | 第87-93页 |
Chapter 3. Synthesis,electrochemical and anti-migration properties of ferrocene-based compounds and their application as burning rate catalysts | 第93-132页 |
3.1 Introduction | 第93-95页 |
3.2 Experimental | 第95-98页 |
3.2.1 Materials | 第95页 |
3.2.2 Synthesis | 第95-97页 |
3.2.3 Characterization | 第97-98页 |
3.3 Results and discussion | 第98-125页 |
3.3.1 Synthesis and characterization of ferrocene-based compounds | 第98-104页 |
3.3.2 Spectroscopic data of ferrocene-based compounds | 第104-105页 |
3.3.3 Electrochemical behavior of ferrocene-based compounds | 第105-119页 |
3.3.4 Anti-migration studies of ferrocene-based compounds | 第119-122页 |
3.3.5 Burning rate catalytic performance of ferrocene-based compounds | 第122-124页 |
3.3.6 Burning rate catalytic mechanism of ferrocene-based compounds | 第124-125页 |
3.4 Conclusion | 第125-126页 |
References | 第126-132页 |
Chapter 4. Synthesis,electrochemical and anti-migration properties of ethylene diamine-based ferrocene terminated dendrimers and their application as burning rate catalysts | 第132-161页 |
4.1 Introduction | 第132-134页 |
4.2 Experimental | 第134-137页 |
4.2.1 Materials | 第134页 |
4.2.2 Synthesis | 第134-135页 |
4.2.3 Characterization | 第135-137页 |
4.3 Results and discussion | 第137-155页 |
4.3.1 Synthesis and characterization of ethylene diamine-based ferrocene terminated dendrimers | 第137-143页 |
4.3.2 Electrochemical behavior of ethylene diamine-based ferrocene terminated dendrimers | 第143-149页 |
4.3.3 Anti-migration studies of ethylene diamine-based ferrocene terminated dendrimers | 第149-152页 |
4.3.4 Burning rate catalytic performance of ethylene diamine-based ferrocene terminated dendrimers | 第152-154页 |
4.3.5 Burning rate catalytic mechanism of ethylene diamine-based ferrocene terminated dendrimers | 第154-155页 |
4.4 Conclusion | 第155-156页 |
References | 第156-161页 |
Chapter 5. Synthesis, electrochemical and anti-migration properties of tris(2-aminoethyl)amine-based ferrocene terminated dendrimers and their application as burning rate catalysts | 第161-185页 |
5.1 Introduction | 第161-162页 |
5.2 Experimental | 第162-165页 |
5.2.1 Materials | 第162-163页 |
5.2.2 Synthesis | 第163-164页 |
5.2.3 Characterization | 第164-165页 |
5.3 Results and discussion | 第165-180页 |
5.3.1 Synthesis and characterization of tris(2-aminoethyl)amine-based ferrocene terminated dendrimers | 第165-170页 |
5.3.2 Electrochemical properties of tris(2-aminoethyl)amine-based ferrocene terminated dendrimers | 第170-175页 |
5.3.3 Anti-migration studies of tris(2-aminoethyl)amine-based ferrocene terminated dendrimers | 第175-176页 |
5.3.4 Catalytic performance of tris(2-aminoethyl)amine-based ferrocene terminated dendrimers | 第176-179页 |
5.3.5 Burning rate catalytic mechanism of tris(2-aminoethyl)amine-based ferrocene terminated dendrimers | 第179-180页 |
5.4 Conclusion | 第180-181页 |
References | 第181-185页 |
Chapter 6. Conclusion | 第185-189页 |
List of abbreviations | 第189-191页 |
Curriculum vitae | 第191-194页 |