论文目录 | |
| 英文摘要 | 第1-6
页 |
| 中文摘要 | 第6-8
页 |
| Part Ⅰ Progress in Synthesis, Curing, Properties, and Application of Bisphenol-S Epoxy Resin | 第8-20
页 |
| 1 Synthesis of BPSER and Its Derivaives | 第8-11
页 |
| 1．1 Preparation of Low Molecular Weight BPSER | 第9
页 |
| 1．2 Preparation of High Molecular Weight BPSER | 第9-10
页 |
| 1．3 Preparation of BPSER Derivatives | 第10-11
页 |
| 2 Curing Mechanism | 第11-14
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| 2．1 Two General Kinetic Models | 第11-12
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| 2．2 Auocatalytic Mechanism | 第12-13
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| 2．3 Diffusion Stage | 第13-14
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| 3 Properties and Application | 第14-20
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| 3．1 Thermal Properties | 第14
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| 3．2 Applied for Adhesive | 第14-15
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| 3．3 Applied for Pulverized Coating | 第15-20
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| Part Ⅱ Kinetics of Epoxy Resin Formation from Bisphenol-A, Bisphenol-S, and Epichlorohydrin | 第20-29
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| 1 Experimental | 第20-21
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| 2 Results and Discussion | 第21-27
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| 2．1 Kinetics of Reaction of ECH with BPA and BPS | 第23-25
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| 2．2 Kinetics of Reaction of Phenol with EG in Oligomer | 第25-27
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| 3 Conclusions | 第27-29
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| Part Ⅲ Curing Kinetics of Bisphenol-S Epoxy Resin and Hardener System | 第29-46
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| 1 Experimental | 第29-31
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| 2 Results and Discussion | 第31-46
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| 2．1 IR Analysis for BPSER/DDS and BPSER/phthalic anhydride System | 第31-32
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| 2．2 Autocatalytic Kinetics Model | 第32-33
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| 2．3 Curing Kinetics Behavior for Amines as Hardener | 第33-39
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| 2．4 Curing Kinetics Behavior for Phthalic Anhydrides as Hardener | 第39-43
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| 2．5 Molecular Mechanism for BPSER/amine Curing System | 第43-44
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| 2．6 Molecular Mechanism for BPSER/anhydride Curing System | 第44-46
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| Part Ⅳ Thermal Characterization of BPSER/hardener Curing System | 第46-60
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| 1 Experimental | 第46-47
页 |
| 2 Results and Discussion | 第47-60
页 |
| 2．1 Isothermal curing by TBA for BPSER/DDM System | 第47-48
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| 2．2 T_g Value and Curing Process | 第48-54
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| 2．2．1 T_g of BPSER/amine System with Cure Degrees | 第48-51
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| 2．2．2 T_g of BPSER/anhydride System with Cure Degrees | 第51-53
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| 2．2．3 Curing Process of BPSER Modified BPAER/DDM System | 第53-54
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| 2．3 Thermal Degradation Kinetics | 第54-60
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| 2．3．1 BPSER/amine Cured System | 第54-56
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| 2．3．2 BPSER/anhydride Cured System | 第56-60页 |
